IndiumV3, Main, Repository, bibRecord, 003F42

InIII-Catalysed Tandem C-C and C-O Bond Formation between Phenols and Allylic Acetates

Identifieur interne : 003F42 ( Main/Repository ); précédent : 003F41; suivant : 003F43

InIII-Catalysed Tandem C-C and C-O Bond Formation between Phenols and Allylic Acetates

Auteurs : RBID : Pascal:11-0111505

Descripteurs français

Pascal (Inist)
- Réaction catalytique, Réaction tandem, Phénols, Composé allylique, Allylation, Réaction intramoléculaire, Alcoxylation, Catalyseur, Condition opératoire modérée, Dérivé du chromane, Cinétique, Mécanisme réaction, Etude théorique, Indium, Acide Lewis, Hétérocycle oxygène, Triflate d'indium, Benzopyrane dérivé.

English descriptors

KwdEn :
- Alkoxylation, Allylation, Allylic compound, Catalyst, Catalytic reaction, Chroman derivatives, Indium, Intramolecular reaction, Kinetics, Lewis acid, Mild operating conditions, Oxygen heterocycle, Phenols, Reaction mechanism, Tandem reaction, Theoretical study.

Abstract

Indium triflate catalysed tandem allylation-intramolecular hydroalkoxylation was efficiently carried out by using 1 mol-% of the catalyst under mild conditions to afford the dihydrobenzopyran ring system (chroman-type structure) in good yields. Kinetic, mechanistic and theoretical studies are also presented.

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Pascal:11-0111505

Le document en format XML

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-Catalysed Tandem C-C and C-O Bond Formation between Phenols and Allylic Acetates</title>
<author><name sortKey="Vece, Vito" uniqKey="Vece V">Vito Vece</name>
<affiliation wicri:level="3"><inist:fA14 i1="01"><s1>Laboratoire de Chimie des Molécules Bioactives et des Arômes, Université de Nice-Sophia Antipolis, CNRS, UMR 6001, Institut de Chimie de Nice, Parc Valrose</s1>
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<author><name sortKey="Ricci, Jeremy" uniqKey="Ricci J">Jérémy Ricci</name>
<affiliation wicri:level="3"><inist:fA14 i1="01"><s1>Laboratoire de Chimie des Molécules Bioactives et des Arômes, Université de Nice-Sophia Antipolis, CNRS, UMR 6001, Institut de Chimie de Nice, Parc Valrose</s1>
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<author><name sortKey="Poulain Martini, Sophie" uniqKey="Poulain Martini S">Sophie Poulain-Martini</name>
<affiliation wicri:level="3"><inist:fA14 i1="01"><s1>Laboratoire de Chimie des Molécules Bioactives et des Arômes, Université de Nice-Sophia Antipolis, CNRS, UMR 6001, Institut de Chimie de Nice, Parc Valrose</s1>
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<author><name sortKey="Carissan, Yannick" uniqKey="Carissan Y">Yannick Carissan</name>
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<author><name sortKey="Dunach, Elisabet" uniqKey="Dunach E">Elisabet Dunach</name>
<affiliation wicri:level="3"><inist:fA14 i1="01"><s1>Laboratoire de Chimie des Molécules Bioactives et des Arômes, Université de Nice-Sophia Antipolis, CNRS, UMR 6001, Institut de Chimie de Nice, Parc Valrose</s1>
<s2>06108 Nice</s2>
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<placeName><region type="region" nuts="2">Provence-Alpes-Côte d'Azur</region>
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<title level="j" type="main">European journal of organic chemistry : (Print)</title>
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<profileDesc><textClass><keywords scheme="KwdEn" xml:lang="en"><term>Alkoxylation</term>
<term>Allylation</term>
<term>Allylic compound</term>
<term>Catalyst</term>
<term>Catalytic reaction</term>
<term>Chroman derivatives</term>
<term>Indium</term>
<term>Intramolecular reaction</term>
<term>Kinetics</term>
<term>Lewis acid</term>
<term>Mild operating conditions</term>
<term>Oxygen heterocycle</term>
<term>Phenols</term>
<term>Reaction mechanism</term>
<term>Tandem reaction</term>
<term>Theoretical study</term>
</keywords>
<keywords scheme="Pascal" xml:lang="fr"><term>Réaction catalytique</term>
<term>Réaction tandem</term>
<term>Phénols</term>
<term>Composé allylique</term>
<term>Allylation</term>
<term>Réaction intramoléculaire</term>
<term>Alcoxylation</term>
<term>Catalyseur</term>
<term>Condition opératoire modérée</term>
<term>Dérivé du chromane</term>
<term>Cinétique</term>
<term>Mécanisme réaction</term>
<term>Etude théorique</term>
<term>Indium</term>
<term>Acide Lewis</term>
<term>Hétérocycle oxygène</term>
<term>Triflate d'indium</term>
<term>Benzopyrane dérivé</term>
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<front><div type="abstract" xml:lang="en">Indium triflate catalysed tandem allylation-intramolecular hydroalkoxylation was efficiently carried out by using 1 mol-% of the catalyst under mild conditions to afford the dihydrobenzopyran ring system (chroman-type structure) in good yields. Kinetic, mechanistic and theoretical studies are also presented.</div>
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<fA08 i1="01" i2="1" l="ENG"><s1>In<sup>III</sup>
-Catalysed Tandem C-C and C-O Bond Formation between Phenols and Allylic Acetates</s1>
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<s2>06108 Nice</s2>
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<fC01 i1="01" l="ENG"><s0>Indium triflate catalysed tandem allylation-intramolecular hydroalkoxylation was efficiently carried out by using 1 mol-% of the catalyst under mild conditions to afford the dihydrobenzopyran ring system (chroman-type structure) in good yields. Kinetic, mechanistic and theoretical studies are also presented.</s0>
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<s5>03</s5>
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<fC03 i1="04" i2="X" l="FRE"><s0>Composé allylique</s0>
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<s5>04</s5>
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<s5>05</s5>
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<fC03 i1="05" i2="X" l="ENG"><s0>Allylation</s0>
<s5>05</s5>
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<s5>05</s5>
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<s5>07</s5>
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<s5>07</s5>
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<fC03 i1="08" i2="X" l="FRE"><s0>Catalyseur</s0>
<s5>08</s5>
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<fC03 i1="08" i2="X" l="ENG"><s0>Catalyst</s0>
<s5>08</s5>
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<fC03 i1="08" i2="X" l="SPA"><s0>Catalizador</s0>
<s5>08</s5>
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<fC03 i1="09" i2="X" l="FRE"><s0>Condition opératoire modérée</s0>
<s5>09</s5>
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<fC03 i1="09" i2="X" l="ENG"><s0>Mild operating conditions</s0>
<s5>09</s5>
</fC03>
<fC03 i1="09" i2="X" l="SPA"><s0>Condición operatoria moderada</s0>
<s5>09</s5>
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<fC03 i1="10" i2="X" l="FRE"><s0>Dérivé du chromane</s0>
<s2>FR</s2>
<s5>10</s5>
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<s2>FR</s2>
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<s5>12</s5>
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<s5>12</s5>
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<fC03 i1="12" i2="X" l="ENG"><s0>Reaction mechanism</s0>
<s5>13</s5>
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<fC03 i1="12" i2="X" l="SPA"><s0>Mecanismo reacción</s0>
<s5>13</s5>
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<s5>14</s5>
</fC03>
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<s5>14</s5>
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<s5>14</s5>
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<s2>NC</s2>
<s5>15</s5>
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<s2>NC</s2>
<s5>15</s5>
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<fC03 i1="14" i2="X" l="SPA"><s0>Indio</s0>
<s2>NC</s2>
<s5>15</s5>
</fC03>
<fC03 i1="15" i2="X" l="FRE"><s0>Acide Lewis</s0>
<s5>16</s5>
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<fC03 i1="15" i2="X" l="ENG"><s0>Lewis acid</s0>
<s5>16</s5>
</fC03>
<fC03 i1="15" i2="X" l="SPA"><s0>Acido Lewis</s0>
<s5>16</s5>
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<fC03 i1="16" i2="X" l="FRE"><s0>Hétérocycle oxygène</s0>
<s5>17</s5>
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<fC03 i1="16" i2="X" l="ENG"><s0>Oxygen heterocycle</s0>
<s5>17</s5>
</fC03>
<fC03 i1="16" i2="X" l="SPA"><s0>Heterociclo oxígeno</s0>
<s5>17</s5>
</fC03>
<fC03 i1="17" i2="X" l="FRE"><s0>Triflate d'indium</s0>
<s4>INC</s4>
<s5>62</s5>
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<fC03 i1="18" i2="X" l="FRE"><s0>Benzopyrane dérivé</s0>
<s4>INC</s4>
<s5>63</s5>
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<fN21><s1>073</s1>
</fN21>
</pA>
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</record>

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InIII-Catalysed Tandem C-C and C-O Bond Formation between Phenols and Allylic Acetates

InIII-Catalysed Tandem C-C and C-O Bond Formation between Phenols and Allylic Acetates

Descripteurs français

English descriptors

Abstract

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